What does hydroacylation mean?
Definitions for hydroacylation
hy·droa·cy·la·tion
This dictionary definitions page includes all the possible meanings, example usage and translations of the word hydroacylation.
Wiktionary
hydroacylationnoun
Any addition reaction in which an acyl group and a hydrogen atom (from an aldehyde) are added across a double bond
Wikidata
Hydroacylation
Hydroacylation is a type of organic reaction in which an aldehyde is added over an alkene or alkyne bond. The reaction product is a ketone. The reaction requires a metal catalyst and intramolecular reaction is favored over an intermolecular one. With alkynes the reaction product is an cyclopentenone. The reaction was discovered by K. Sakai in 1972 as part in a synthetic route to certain prostanoids. The reagent in this reaction was tin tetrachloride. With an stoichiometric amount of Wilkinson's catalyst in chloroform, acetonitrile or benzene an equal amount of a cyclopropane was formed as the result of decarbonylation. The first catalytic application was reported by Miller in 1976 in the reaction of 4-pentenal with Wilkinson's catalyst to form cyclopentanone. In this reaction the solvent was saturated with ethylene. Cyclopentane ring-formation is favored, the reaction product of 5-pentenal is again a cyclopentanone. Another suitable catalyst is cationic rhodium compound RhClO4
Numerology
Chaldean Numerology
The numerical value of hydroacylation in Chaldean Numerology is: 9
Pythagorean Numerology
The numerical value of hydroacylation in Pythagorean Numerology is: 8
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"hydroacylation." Definitions.net. STANDS4 LLC, 2024. Web. 26 Apr. 2024. <https://www.definitions.net/definition/hydroacylation>.
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