What does luche reduction mean?
Definitions for luche reduction
luche re·duc·tion
This dictionary definitions page includes all the possible meanings, example usage and translations of the word luche reduction.
Wikipedia
Luche reduction
Luche reduction is the selective organic reduction of α,β-unsaturated ketones to allylic alcohols with sodium borohydride (NaBH4) and lanthanide chlorides, mainly cerium(III) chloride (CeCl3), in methanol or ethanol. The Luche reduction can be conducted chemoselectively toward ketone in the presence of aldehyde or toward α,β-unsaturated ketone in the presence of non-conjugated ketone.An enone forms an allylic alcohol in a 1,2-addition, and the competing conjugate 1,4-addition is suppressed. The selectivity can be explained in terms of the HSAB theory: carbonyl groups require hard nucleophiles for 1,2-addition. The hardness of the borohydride is increased by replacing hydride groups with alkoxide groups, a reaction catalyzed by the cerium salt by increasing the electrophilicity of the carbonyl group. This is selective for ketones because they are more Lewis basic. In one application, a ketone is selectively reduced in the presence of an aldehyde. Actually, in the presence of methanol as solvent, the aldehyde forms methoxy acetal that is inactive in the reducing conditions.
Numerology
Chaldean Numerology
The numerical value of luche reduction in Chaldean Numerology is: 5
Pythagorean Numerology
The numerical value of luche reduction in Pythagorean Numerology is: 5
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"luche reduction." Definitions.net. STANDS4 LLC, 2024. Web. 19 Apr. 2024. <https://www.definitions.net/definition/luche+reduction>.
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