What does regioselectivity mean?
Definitions for regioselectivity
re·gios·e·lec·tiv·i·ty
This dictionary definitions page includes all the possible meanings, example usage and translations of the word regioselectivity.
Wiktionary
regioselectivitynoun
The condition of being regioselective
regioselectivitynoun
The degree to which a reaction if regioselective
Wikipedia
Regioselectivity
In chemistry, regioselectivity is the preference of chemical bonding or breaking in one direction over all other possible directions. It can often apply to which of many possible positions a reagent will affect, such as which proton a strong base will abstract from an organic molecule, or where on a substituted benzene ring a further substituent will be added. A specific example is a halohydrin formation reaction with 2-propenylbenzene: Because of the preference for the formation of one product over another, the reaction is selective. This reaction is regioselective because it selectively generates one constitutional isomer rather than the other. Various examples of regioselectivity have been formulated as rules for certain classes of compounds under certain conditions, many of which are named. Among the first introduced to chemistry students are Markovnikov's rule for the addition of protic acids to alkenes, and the Fürst-Plattner rule for the addition of nucleophiles to derivatives of cyclohexene, especially epoxide derivatives.Regioselectivity in ring-closure reactions is subject to Baldwin's rules. If there are two or more orientations that can be generated during a reaction, one of them is dominant (e.g., Markovnikov/anti-Markovnikov addition across a double bond) Regioselectivity can also be applied to specific reactions such as addition to pi ligands. Selectivity also occurs in carbene insertions, for example in the Baeyer-Villiger reaction. In this reaction, an oxygen is regioselectively inserted near an adjacent carbonyl group. In ketones, this insertion is directed toward the carbon which is more highly substituted (i.e. according to Markovnikov's rule). For example, in a study involving acetophenones, this oxygen was preferentially inserted between the carbonyl and the aromatic ring to give acetyl aromatic esters instead of methyl benzoates.
Wikidata
Regioselectivity
In chemistry, regioselectivity is the preference of one direction of chemical bond making or breaking over all other possible directions. It can often apply to which of many possible positions a reagent will affect, such as which proton a strong base will abstract from an organic molecule, or where on a substituted benzene ring a further substituent will add. A specific example is a halohydrin formation reaction with 2-propenylbenzene: Because of the preference for the formation of one product over another, the reaction is selective. This reaction is regioselective because it selectively generates one constitutional isomer rather than the other. Certain examples of regioselectivity have been formulated as rules for certain classes of compounds under certain conditions, many of which are named. Among the first introduced to chemistry students are Markovnikov's rule for the addition of protic acids to alkenes, and the Fürst-Plattner rule for the addition of nucleophiles to derivatives of cyclohexene, especially epoxide derivatives. Regioselectivity in ring-closure reactions is subject to Baldwin's rules. If there are two or more orientations that can be generated during a reaction, one of them is dominant
Numerology
Chaldean Numerology
The numerical value of regioselectivity in Chaldean Numerology is: 9
Pythagorean Numerology
The numerical value of regioselectivity in Pythagorean Numerology is: 5
Translations for regioselectivity
From our Multilingual Translation Dictionary
- regioselectivityHindi
- regioszelektivitásHungarian
- regioselektivitasIndonesian
- региоселективностьRussian
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"regioselectivity." Definitions.net. STANDS4 LLC, 2024. Web. 19 Apr. 2024. <https://www.definitions.net/definition/regioselectivity>.
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