# Definitions for **r factor**

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R-factor

In crystallography, the R-factor is a measure of the agreement between the crystallographic model and the experimental X-ray diffraction data. In other words, it is a measure of how well the refined structure predicts the observed data. The value is also sometimes called the discrepancy index, as it mathematically describes the difference between the experimental observations and the ideal calculated values. It is defined by the following equation: where F is the so-called structure factor and the sum extends over all the reflections measured and their calculated counterparts respectively. The structure factor is closely related to the intensity of the reflection it describes: The minimum possible value is zero, indicating perfect agreement between experimental observations and the structure factors predicted from the model. There is no theoretical maximum, but in practice, values are considerably less than one even for poor models, provided the model includes a suitable scale factor. Random experimental errors in the data contribute to even for a perfect model, and these have more leverage when the data are weak or few, such as for a low-resolution data set.

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"r factor." *Definitions.net.* STANDS4 LLC, 2015. Web. 31 Mar. 2015. <http://www.definitions.net/definition/r factor>.