| Definition of 'electrolytic analysis' |
The Standard Electrical Dictionary |
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1. electrolytic analysis
Chemical analysis by electrolysis. The quantitative separation of a number of metals can be very effectively executed. Thus, suppose that a solution of copper sulphate was to be analyzed. A measured portion of the solution would be introduced into a weighed platinum vessel. The vessel would be connected to the zinc plate terminal of a battery. From the other terminal of the battery a wire would be brought and would terminate in a plate of platinum. This would be immersed in the solution in the vessel. As the current would pass the copper sulphate would be decomposed and eventually all the copper would be deposited in a firm coating on the platinum. The next operations would be to wash the metal with distilled water, and eventually with alcohol, to dry and to weigh the dish with the adherent copper. On subtracting the weight of the dish alone from the weight of the dish and copper, the weight of the metallic copper in the solution would be obtained.
In similar ways many other determinations are effected. The processes of analysis include solution of the ores or other substances to be analyzed and their conversion into proper form for electrolysis. Copper as just described can be precipitated from the solution of its sulphate. For iron and many other metals solutions of their double alkaline oxalates are especially available forms for analysis.
The entire subject has been worked out in considerable detail by Classen, to whose works reference should be made for details of processes.
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Definitions of electrolytic analysis
