What does Aromaticity mean?

Definitions for Aromaticity
aro·matic·i·ty

This dictionary definitions page includes all the possible meanings, example usage and translations of the word Aromaticity.

Wiktionary

  1. aromaticitynoun

    The property of organic compounds which have at least one conjugated ring of alternate single bond and double bonds, and exhibit extreme stability.

Wikipedia

  1. Aromaticity

    In chemistry, aromaticity is a chemical property of cyclic (ring-shaped), typically planar (flat) molecular structures with pi bonds in resonance (those containing delocalized electrons) that gives increased stability compared to saturated compounds having single bonds, and other geometric or connective non-cyclic arrangements with the same set of atoms. Aromatic rings are very stable and do not break apart easily. Organic compounds that are not aromatic are classified as aliphatic compounds—they might be cyclic, but only aromatic rings have enhanced stability. The term aromaticity with this meaning is historically related to the concept of having an aroma, but is a distinct property from that meaning. Since the most common aromatic compounds are derivatives of benzene (an aromatic hydrocarbon common in petroleum and its distillates), the word aromatic occasionally refers informally to benzene derivatives, and so it was first defined. Nevertheless, many non-benzene aromatic compounds exist. In living organisms, for example, the most common aromatic rings are the double-ringed bases (Purine) in RNA and DNA. An aromatic functional group or other substituent is called an aryl group. In terms of the electronic nature of the molecule, aromaticity describes a conjugated system often represented in Lewis diagrams as alternating single and double bonds in a ring. In reality, the electrons represented by the double bonds in the Lewis diagram are actually distributed evenly around the ring ("delocalized"), increasing the molecule's stability. Due to the restrictions imposed by the way Lewis diagrams are drawn, the molecule cannot be represented by one diagram, but rather a hybrid of multiple different diagrams (called resonance), such as with the two resonance structures of benzene. These molecules cannot be found in either one of these representations, with the longer single bonds in one location and the shorter double bond in another (see § Theory below). Rather, the molecule exhibits all equal bond lengths in between those of single and double bonds. This commonly seen model of aromatic rings, namely the idea that benzene was formed from a six-membered carbon ring with alternating single and double bonds (cyclohexatriene), was developed by August Kekulé (see § History below). The model for benzene consists of two resonance forms, which corresponds to the double and single bonds superimposing to produce six one-and-a-half bonds. Benzene is a more stable molecule than would be expected without accounting for charge delocalization.

Wikidata

  1. Aromaticity

    In organic chemistry, aromaticity is a chemical property describing the way in which a conjugated ring of unsaturated bonds, lone pairs, or empty orbitals exhibits a stabilization stronger than would be expected by the stabilization of conjugation alone. The earliest use of the term was in an article by August Wilhelm Hofmann in 1855. There is no general relationship between aromaticity as a chemical property and the olfactory properties of such compounds. Aromaticity can also be considered a manifestation of cyclic delocalization and of resonance. This is usually considered to be because electrons are free to cycle around circular arrangements of atoms that are alternately single- and double-bonded to one another. These bonds may be seen as a hybrid of a single bond and a double bond, each bond in the ring identical to every other. This commonly seen model of aromatic rings, namely the idea that benzene was formed from a six-membered carbon ring with alternating single and double bonds, was developed by Kekulé. The model for benzene consists of two resonance forms, which corresponds to the double and single bonds superimposing to give rise to six one-and-a-half bonds. Benzene is a more stable molecule than would be expected without accounting for charge delocalization.

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Numerology

  1. Chaldean Numerology

    The numerical value of Aromaticity in Chaldean Numerology is: 2

  2. Pythagorean Numerology

    The numerical value of Aromaticity in Pythagorean Numerology is: 8

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"Aromaticity." Definitions.net. STANDS4 LLC, 2024. Web. 19 Apr. 2024. <https://www.definitions.net/definition/Aromaticity>.

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