Wiktionary

1. A to Z(Noun)

   Any of a set of street maps of most British towns and cities; properly the Geographer's Au2013Z Street Atlas

2. A to Z(Noun)

   All facts related to a subject

3. A to Z(Noun)

   An encyclopedic or comprehensive guide

4. A to Z(Adverb)

   Alphabetical order; lexical order

5. A to Z(Adverb)

   From beginning to the end.

6. A to Z(Adverb)

   Over the entirety; completely.